SYNTHESIS OF A 2-HYDROXYMETHYL-DIHYDROPYRIDONE-SYSTEM AS A FLEXIBLE BUILDING-BLOCK FOR THE PREPARATION OF AZASUGARS

被引：30

作者：

ALTENBACH, HJ

WISCHNAT, R

机构：

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 28期

关键词：

D O I：

10.1016/0040-4039(95)00957-E

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

mCPBA induced oxidative cyclization of the aminoalcohol 1a under complete stereocontrol, generating after acetal formation a new diastereomerically pure key intermediate 2b for the flexible synthesis of azasugars. 2b could be converted to protected rac-mannonojirimycin 3 in only three steps.

引用

页码：4983 / 4984

页数：2

共 12 条

[1] STEREOSELECTIVE TOTAL SYNTHESIS OF METHYL ALPHA-D-GLUCOPYRANOSIDES AND ALPHA-L-GLUCOPYRANOSIDES [J].