OXIDATIVE-ADDITION REACTIONS OF ALKYL CHLORIDES WITH CHLOROBIS(CYCLOOCTENE)RHODIUM(I) AND THE BIS(OXAZOLINYL)PYRIDINE LIGAND - FORMATION OF STABLE (CHLOROMETHYL)RHODIUM(III) COMPLEXES AND THEIR REACTIONS

被引：56

作者：

NISHIYAMA, H

HORIHATA, M

HIRAI, T

WAKAMATSU, S

ITOH, K

机构：

[1] School of Materials Science, Toyohashi University of Technology, Toyohashi 441, Tempaku-cho

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 08期

关键词：

D O I：

10.1021/om00054a036

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Dichloromethane and chloroform readily react with chlorobis(cyclooctene)rhodium(I) (1) and 2,6-bis-(4,4-dimethyloxazolin-2-yl)pyridine, dm-pybox, at room temperature to give the stable (chloromethyl)-rhodium(III) complex 2 and (dichloromethyl)rhodium(III) complex 4, respectively. Several organic halides also react with 1 to give the corresponding substituted alkylrhodium(III) complexes. Some reactions of the chloromethyl complexes were also demonstrated. Decomposition of 2 and 3 in methanol at 100-130-degrees-C gave the methylrhodium(III) complex, in which the origin of the methyl group can be traced to be methanol.

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页码：2706 / 2708

页数：3

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