SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURE OF OS3(CO)9[1,1,1-TRIS(ISOCYANOMETHYL)ETHANE] - A NOVEL TRIS-ISOCYANIDE LIGAND CAPPED TRIOSMIUM CLUSTER

被引：8

作者：

CONSTABLE, EC

JOHNSON, BFG

KHAN, FK

LEWIS, J

RAITHBY, PR

MIKULCIK, P

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

[2] TECH UNIV MUNICH,INST INORGAN CHEM,W-8046 GARCHING,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 403卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(91)83111-G

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of 1,1,1-tris(isocyanomethyl)ethane (trisNC) (3) with [Os3(CO)10(NCMe)2] gives the tripod-capped cluster [Os3(CO)9(trisNC)] (4), which has been fully characterised by spectroscopic and X-ray crystallographic techniques.

引用

页码：C15 / C18

页数：4

共 10 条

[1] TRIOSMIUM CLUSTER COMPOUNDS CONTAINING ISOCYANIDE AND HYDRIDE LIGANDS - CRYSTAL AND MOLECULAR-STRUCTURES OF (MU-H)(H)OS3(CO)10(CN-T-C4H9) AND (MU-H)2OS3(CO)9(CN-T-C4H9) [J].

ADAMS, RD ;

GOLEMBESKI, NM .

INORGANIC CHEMISTRY, 1979, 18 (07) :1909-1912

[2] THE SYNTHESIS, STRUCTURES, BONDING AND UNUSUAL REACTIVITY OF SULFIDO OSMIUM CARBONYL CLUSTER COMPOUNDS [J].

ADAMS, RD .

POLYHEDRON, 1985, 4 (12) :2003-2025

[3] CLUSTER CHEMISTRY .44. X-RAY STRUCTURES OF [RU3(CO)11(CNBUT)] (AT 130-K) AND [OS3(CO)11(CNBUT)] (AT 295-K) [J].

BRUCE, MI ;

PAIN, GN ;

HUGHES, CA ;

PATRICK, JM ;

SKELTON, BW ;

WHITE, AH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1986, 307 (03) :343-350

[4] STRUCTURAL STUDIES ON POLYNUCLEAR OSMIUM CARBONYL HYDRIDES .1. CRYSTAL-STRUCTURES OF ISOMORPHOUS SPECIES H2OS3(CO)11 AND OS3(CO)12 - DIRECT INFORMATION ON ROLE OF AN EQUATORIAL MU-2-BRIDGING HYDRIDE LIGAND IN PERTURBING ARRANGEMENT OF CARBONYL LIGANDS IN A TRIANGULAR CLUSTER [J].

CHURCHILL, MR ;

DEBOER, BG .

INORGANIC CHEMISTRY, 1977, 16 (04) :878-884

[5]

CONNOR JA, 1980, TRANSITION METAL CLU

[6] CAPPED TRI-RUTHENIUM CARBONYL CLUSTER - X-RAY CRYSTAL-STRUCTURE OF [RU3(CO)9[MESI(PBU2)3]] [J].

DEBOER, JJ ;

VANDOORN, JA ;

MASTERS, C .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (22) :1005-1006

[7]

DRAKE SR, 1989, INORG SYNTH, V26, P292

[8]

FLEISCHER EB, 1971, J ORG CHEM, V36, P3043

[9] TRANSITION-METAL-MEDIATED PHOSPHORUS CARBON BOND-CLEAVAGE AND ITS RELEVANCE TO HOMOGENEOUS CATALYST DEACTIVATION [J].

GARROU, PE .

CHEMICAL REVIEWS, 1985, 85 (03) :171-185

[10] SYNTHESIS AND METAL-CARBONYL COMPLEXES OF CIS,CIS-1,3,5-TRIISOCYANOCYCLOHEXANE, AN UNUSUAL TRIDENTATE LIGAND [J].

MICHELIN, RA ;

ANGELICI, RJ .

INORGANIC CHEMISTRY, 1980, 19 (12) :3853-3856

← 1 →