OXIDATIVE ADDITION OF N-SUBSTITUTED AMIDES TO MOLYBDENUM(II) INVOLVING N-H BOND-CLEAVAGE TO GIVE (ETA-2-N-ACYLAMIDO-N,O)HYDRIDOMOLYBDENUM(II) COMPLEXES - X-RAY MOLECULAR-STRUCTURE OF THE 7-COORDINATE COMPLEX [MOH(N(COCH3)CH3)((C6H5)2PCH2CH2P(C6H5)2)2]

被引：11

作者：

ITO, T ^{[1
]}

KURISHIMA, S ^{[1
]}

TANAKA, M ^{[1
]}

OSAKADA, K ^{[1
]}

机构：

[1] TOKYO INST TECHNOL,RESOURCES UTILIZAT RES LAB,MIDORI KU,YOKOHAMA,KANAGAWA 227,JAPAN

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 07期

关键词：

D O I：

10.1021/om00043a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Photochemical or thermal reaction of [MoH4(dppe)2] with N-alkylamides R1NHCOR2 (R1, R2: Me, Me; Ph, Me; Me, H; Ph, H; (CH2)3; Ph, Ph) in benzene or toluene yielded [MoH{N(R1)COR2-N,O}(dppe)2] as a result of the oxidative addition involving amide N-H bond cleavage (dppe = Ph2PCH2CH2PPh2). The resulting N-acylamido complexes have been characterized by means of NMR and IR spectroscopy as well as with an X-ray crystal structure study for R1, R2 = Me, Me. Some reactions of the N-acylamido complexes, including the oxidation of MeOH to yield a formaldehyde-coordinated complex, are also described.

引用

页码：2333 / 2335

页数：3

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