METAL-ALKENE PI-CHELATION - A STEREODIRECTING EFFECT IN ALLYLZINCATION REACTIONS AND IN ZINC MEDIATED CYCLOPROPANATIONS

被引：33

作者：

MAREK, I

BERUBEN, D

NORMANT, JF

机构：

[1] Laboratoire de Chimie des Organoéléments, associé au C.N.R.S., Tour 44-45 Université P. et M. Curie, 75252 Paris Cedex 05

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 21期

关键词：

D O I：

10.1016/0040-4039(95)00614-I

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A pi-chelation between an olefinic site and a zinc atom gamma to this unsaturation governs the allylzincation reactions and 1,3-elimination reactions from organogembismetallic reagents.

引用

页码：3695 / 3698

页数：4

共 26 条

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