PHOTOINDUCED ELECTRON-TRANSFER REACTION OF 7-BENZHYDRYLIDENENORBORNENE - CHEMICAL CAPTURE OF A RADICAL CATION INTERMEDIATE WITH NONCLASSICAL CATION CHARACTER

被引：14

作者：

HIRANO, T ^{[1
]}

SHIINA, S ^{[1
]}

OHASHI, M ^{[1
]}

机构：

[1] UNIV ELECTROCOMMUN,DEPT APPL PHYS & CHEM,CHOFU,TOKYO 182,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 21期

关键词：

D O I：

10.1039/c39920001544

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A photoinduced electron-transfer reaction of benzhydrylidenenorbornene 1 as an electron donor gives the radical cation 1+., which could be captured chemically by methanol or by the intramolecular hydroxy group, indicating the existence of a strong homoconjugative interaction between the exocyclic double bond and the C(2)-C(3) double bond.

引用

页码：1544 / 1545

页数：2

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