ONE-ELECTRON REDUCTION POTENTIAL AND RING-OPENING OF THE SUCCINIMIDYL RADICAL IN WATER

被引：37

作者：

LIND, J

JONSSON, M

ERIKSEN, TE

MERENYI, G

EBERSON, L

机构：

[1] ROYAL INST TECHNOL,DEPT PHYS CHEM,S-10044 STOCKHOLM 70,SWEDEN

[2] UNIV LUND,CTR CHEM,DIV ORGAN CHEM 3,S-22100 LUND,SWEDEN

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1993年 / 97卷 / 08期

关键词：

D O I：

10.1021/j100110a023

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

By means of pulse radiolysis in water, N-chlorosuccinimide (SCl) was reduced in a one-electron step to yield the succinimidyl radical, S., via the intermediacy of the radical anion, SCl.-. The rate of ring opening of S. was measured to be 8 x 10(4) s-1. By equilibration with Cl2.-/2Cl-, the one-electron reduction potential of S. was determined to be 2.22 +/- 0.02 V vs NHE. From this value and other data, the N-H bond strength in succinimide was calculated to be 118 +/- 3 kcal/mol.

引用

页码：1610 / 1614

页数：5

共 38 条

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