PREPARATION AND CHARACTERIZATION OF AN (IODOBUTOXY)[HYDRIDOTRIS(3,5-DIMETHYLPYRAZOL-1-YL)BORATE]URANIUM COMPLEX

被引：14

作者：

COLLIN, J ^{[1
]}

DEMATOS, AP ^{[1
]}

SANTOS, I ^{[1
]}

机构：

[1] ICEN,LNETI,DEPT QUIM,P-2686 SACAVEM,PORTUGAL

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 463卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)83405-K

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

During the reaction of a uranium pellet with freshly sublimed elemental iodine in THF, ring opening of the THF was observed and a U-IV species was obtained. Further reaction of the solution with Na[HB(3,5Me(2)pz)(3)] in THF at room temperature gave, after recrystallization, a green crystalline solid 2 formulated as [UI2{O(CH2)(4)I}{HB(3,5-Me(2)pz)(3)}] on the basis of various analyses. This complex has also been prepared by reaction of UI4 in THF with the potassium salt of the polypyrazolylborate. The mechanism of the ring-opening of THF is discussed.

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页码：103 / 107

页数：5

相关论文

共 31 条

[1]

ALMEIDA T, 1987, THESIS U LISBOA

[2] IODO-COMPLEXES OF THORIUM(4) AND URANIUM(4) [J].

BAGNALL, KW ;

BROWN, D ;

JONES, PJ ;

DUPREEZ, JGH .

JOURNAL OF THE CHEMICAL SOCIETY, 1965, (JAN) :350-&

[3] ACTINIDE POLY(PYRAZOL-1-YL)BORATE COMPLEXES - SYNTHESIS AND STRUCTURE OF HYDROTRIS(3,5-DIMETHYLPYRAZOL-1-YL)BORATOTRICHLOROTETRAHYDROFURAN ACTINIDE(IV), TH[HB(3,5-ME2PZ)3]CL3(THF), U[HB(3,5-ME2PZ)3]CL3(THF) [J].

BALL, RG ;

EDELMANN, F ;

MATISONS, JG ;

TAKATS, J ;

MARQUES, N ;

MARCALO, J ;

DEMATOS, AP ;

BAGNALL, KW .

INORGANICA CHIMICA ACTA, 1987, 132 (01) :137-143

[4]

BHATT MV, 1984, TETRAHEDRON LETT, V25, P3497

[5] DIHYDROBIS(3,5-DIMETHYLPYRAZOLYL)BORATE DERIVATIVES OF F-ELEMENTS [J].

CARVALHO, A ;

DOMINGOS, A ;

GASPAR, P ;

MARQUES, N ;

DEMATOS, AP ;

SANTOS, I .

POLYHEDRON, 1992, 11 (12) :1481-1488

[6] FACILE SOLUTION ROUTES TO HYDROCARBON-SOLUBLE LEWIS BASE ADDUCTS OF THORIUM TETRAHALIDES - SYNTHESIS, CHARACTERIZATION, AND X-RAY STRUCTURE OF THBR4(THF)4 [J].

CLARK, DL ;

FRANKCOM, TM ;

MILLER, MM ;

WATKIN, JG .

INORGANIC CHEMISTRY, 1992, 31 (09) :1628-1633

[7] LEWIS BASE ADDUCTS OF URANIUM TRIIODIDE - A NEW CLASS OF SYNTHETICALLY USEFUL PRECURSORS FOR TRIVALENT URANIUM CHEMISTRY [J].

CLARK, DL ;

SATTELBERGER, AP ;

BOTT, SG ;

VRTIS, RN .

INORGANIC CHEMISTRY, 1989, 28 (10) :1771-1773

[8]

DEMATOS AP, UNPUB

[9] ACTINIDE POLY(PYRAZOL-1-YL)BORATE COMPLEXES - SYNTHESIS AND CHARACTERIZATION OF HYDROTRIS(3,5-DIMETHYLPYRAZOL-1-YL)BORATE ACTINIDE(IV) ARYLOXIDES [J].

DOMINGOS, A ;

MARCALO, J ;

MARQUES, N ;

DEMATOS, AP ;

TAKATS, J ;

BAGNALL, KW .

JOURNAL OF THE LESS-COMMON METALS, 1989, 149 (1-2) :271-277

[10] BIS[HYDROTRIS(PYRAZOLYL)BORATO]DICHLOROACTINIDE(IV) COMPLEXES - X-RAY CRYSTAL-STRUCTURES OF THCL2(HBPZ3)2 AND UCL2(HBPZ3)2 [J].

DOMINGOS, A ;

MARCALO, J ;

SANTOS, I ;

DEMATOS, AP .

POLYHEDRON, 1990, 9 (14) :1645-1652

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