CONFORMATIONAL EQUILIBRIUM IN 3-METHOXYPHENOL - A MICROWAVE SPECTROSCOPY STUDY

被引：20

作者：

CAMINATI, W ^{[1
]}

MELANDRI, S ^{[1
]}

FAVERO, LB ^{[1
]}

机构：

[1] CNR,IST SPETTROSCOPIA MOLEC,I-40126 BOLOGNA,ITALY

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1993年 / 161卷 / 02期

关键词：

D O I：

10.1006/jmsp.1993.1248

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The microwave spectra of 3-methoxyphenol and of its O-D monodeuterated species have been investigated in the frequency range 28-40 GHz. Of the four possible conformers upon rotation of the hydroxy and methoxy groups only one has been observed. Three vibrational satellites of the methoxy group torsion have been analyzed and the local potential energy surface has been determined. © 1993 Academic Press, Inc.

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页码：427 / 434

页数：8

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