PHOTOLYTIC FORMATION OF ISOMERIC VINYL RADICALS FROM CIS- AND TRANS-VINYL IODIDES

被引：29

作者：

NEUMAN, RC

HOLMES, GD

机构：

[1] Department of Chemistry, University of California, Riverside

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1968年 / 33卷 / 12期

关键词：

D O I：

10.1021/jo01276a001

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The isomeric vinyl iodides cis- and trans-4-iodo-3-heptenes have been synthesized, and their comparative solution phase photochemistry has been investigated using chloroform and pentane as solvents. Both isomers gave 3-heptyne and cis- and trans-3-heptenes as major products; the iodides isomerized; and 3,4-heptadiene was observed as a product under certain conditions. The product distributions were isomer and solvent dependent. The results are discussed in terms of the primary formation of vibrationally excited cis- and trans-3-hepten-4-yl radicals and their secondary reactions. © 1968, American Chemical Society. All rights reserved.

引用

页码：4317 / &

共 46 条

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