NEW CLASS OF PLANAR-LOCKED POLYENE DYES FOR NONLINEAR OPTICS

被引：41

作者：

CABRERA, I ^{[1
]}

ALTHOFF, O ^{[1
]}

MAN, HT ^{[1
]}

YOON, HN ^{[1
]}

机构：

[1] HOECHST CELANESE CORP, DIV RES, SUMMIT, NJ 07901 USA

来源：

ADVANCED MATERIALS | 1994年 / 6卷 / 01期

关键词：

D O I：

10.1002/adma.19940060106

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A combination of strategies for optimizing the molecular hyperpolarizability have been employed in the design of the molecules reported here: an aromatic moiety is linked to a planar-fixed polyene chain. The synthesis and nonlinear optical (NLO) characterization (absorption and electric-field-induced second harmonic generation) of the materials are described and their NLO properties compared-favorably-with those of 4'-dimethylamino-4-nitrostilbene, the prototypical organic material for electrooptic devices based on poled polymers.

引用

页码：43 / 45

页数：3

共 19 条

[1] BUCKLEY A, 1986, POLYM MAT SCI ENG, V54, P502
[2] REGIOSPECIFIC REDUCTION OF UNSATURATED CONJUGATED KETONES WITH SODIUM DITHIONITE UNDER PHASE-TRANSFER CATALYSIS
CAMPS, F
COLL, J
GUITART, J
[J]. TETRAHEDRON, 1986, 42 (16) : 4603 - 4609
[3] EXPERIMENTAL INVESTIGATIONS OF ORGANIC MOLECULAR NONLINEAR OPTICAL POLARIZABILITIES .1. METHODS AND RESULTS ON BENZENE AND STILBENE DERIVATIVES
CHENG, LT
TAM, W
STEVENSON, SH
MEREDITH, GR
RIKKEN, G
MARDER, SR
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (26) : 10631 - 10643
[4] DEMARTINO RN, 1989, Patent No. 4808332
[5] USE OF THIAZOLE RINGS TO ENHANCE MOLECULAR 2ND-ORDER NONLINEAR OPTICAL SUSCEPTIBILITIES
DIRK, CW
KATZ, HE
SCHILLING, ML
KING, LA
[J]. CHEMISTRY OF MATERIALS, 1990, 2 (06) : 700 - 705
[6] MAKER FRINGES - A DETAILED COMPARISON OF THEORY AND EXPERIMENT FOR ISOTROPIC AND UNIAXIAL CRYSTALS
JERPHAGNON, J
KURTZ, SK
[J]. JOURNAL OF APPLIED PHYSICS, 1970, 41 (04) : 1667 - +
[7] EFFECTS OF DISPERSION AND FOCUSING ON PRODUCTION OF OPTICAL HARMONICS
MAKER, PD
SAVAGE, CM
TERHUNE, RW
NISENOFF, M
[J]. PHYSICAL REVIEW LETTERS, 1962, 8 (01) : 21 - &
[8] APPROACHES FOR OPTIMIZING THE 1ST ELECTRONIC HYPERPOLARIZABILITY OF CONJUGATED ORGANIC-MOLECULES
MARDER, SR
BERATAN, DN
CHENG, LT
[J]. SCIENCE, 1991, 252 (5002) : 103 - 106
[9] MOLECULAR MATERIALS FOR 2ND-ORDER NONLINEAR-OPTICAL APPLICATIONS
MARDER, SR
PERRY, JW
[J]. ADVANCED MATERIALS, 1993, 5 (11) : 804 - 815
[10] DIRECT OBSERVATION OF REDUCED BOND LENGTH ALTERNATION IN DONOR-ACCEPTOR POLYENES
MARDER, SR
PERRY, JW
TIEMANN, BG
GORMAN, CB
GILMOUR, S
BIDDLE, SL
BOURHILL, G
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (06) : 2524 - 2526

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