BOROPHOSPHATES - A NEGLECTED CLASS OF COMPOUNDS - CRYSTAL-STRUCTURES OF M(II)[BPO5] (M(II)=CA, SR) AND BA-3[BP3O12]

被引：188

作者：

KNIEP, R ^{[1
]}

GOZEL, G ^{[1
]}

EISENMANN, B ^{[1
]}

ROHR, C ^{[1
]}

ASBRAND, M ^{[1
]}

KIZILYALLI, M ^{[1
]}

机构：

[1] MIDDLE EAST TECH UNIV,DEPT CHEM,ANKARA 06531,TURKEY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 07期

关键词：

D O I：

10.1002/anie.199407491

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Vertex‐sharing BO4 and PO4 tetrahedra form the framework of the title compounds. Ca[BPO5] and Sr[BPO5] crystallize in the stillwellite structural type and contain tetrahedral chain anions ∞1[BPO 52−], which can be described as loop‐branched “dreier” single chains. In Ba3[BP3O12] the ∞1tetrahedral anions form “zweifach” open “vierer” single chains. Given these results and the known linking modes of tetrahedral units, it is expected that borophosphates with layered and framework structures, as well as microporous structures, can be found. Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：749 / 751

页数：3

共 20 条

[1] STRUCTURAL INVESTIGATION OF A NEW SERIES OF LONG-CHAIN POLYPHOSPHATES - CRYSTAL-STRUCTURE OF AGK(PO3)2 AND CRYSTAL DATA FOR AGM(PO3)2 WITH M = K, RB, CS, AND TL [J].