SYNTHESIS OF PHENOLIC NATURAL-PRODUCTS USING PALLADIUM-CATALYZED COUPLING REACTIONS

被引:40
作者
BATES, RW
GABEL, CJ
JI, JH
RAMADEVI, T
机构
[1] Department of Chemistry, University of North Texas, Denton
关键词
D O I
10.1016/0040-4020(95)00441-A
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Derivatives of 2,4-diiodophenol are shown to undergo palladium catalyzed carbonylation and alkyne coupling reactions in excellent to moderate yield and high regioselectivity. The scope of these reactions is explored. Palladium catalyzed reactions are employed as the key steps in the synthesis of three phenolic natural products: Plicatin B, Drupanin and Eutypine.
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页码:8199 / 8212
页数:14
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