TEMPORARY ANION STATES IN THE CHLOROMETHANES AND IN MONOCHLOROALKANES

被引：67

作者：

GUERRA, M

JONES, D

DISTEFANO, G

SCAGNOLARI, F

MODELLI, A

机构：

[1] UNIV FERRARA,DIPARTMENTO CHIM,I-44100 FERRARA,ITALY

[2] UNIV BOLOGNA,DIPARTIMENTO CHIM G CIAMICIAN,I-40126 BOLOGNA,ITALY

来源：

JOURNAL OF CHEMICAL PHYSICS | 1991年 / 94卷 / 01期

关键词：

D O I：

10.1063/1.460364

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The resonance energies for electron attachment to the chloromethanes are evaluated by means of bound and continuum multiple scattering X-alpha calculations. The results closely reproduce the experimental electron transmission spectroscopy data and confirm their previous assignment. Electron transmission and dissociative attachment spectra of monochloroalkanes are also reported, in order to obtain information on the effects of branching at the substituted carbon atom and of alkyl chain length on the resonance and chlorine anion production energies.

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页码：484 / 490

页数：7

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