FLUCTUATIONS IN STATE-SELECTED UNIMOLECULAR DECOMPOSITION - DOUBLE-RESONANCE INFRARED VISIBLE PHOTOFRAGMENT YIELD SPECTROSCOPY OF NO2

被引：29

作者：

REID, SA

BRANDON, JT

HUNTER, M

REISLER, H

机构：

[1] Department of Chemistry, University of Southern California, Los Angeles

来源：

JOURNAL OF CHEMICAL PHYSICS | 1993年 / 99卷 / 06期

关键词：

D O I：

10.1063/1.466033

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Fluctuations in the NO(2H) state distributions from the state-selected simple bond fission unimolecular reaction of NO2 are probed using double-resonance photofragment yield (PHOFRY) spectroscopy. These spectra are sensitive probes of the correlation of selected NO rovibronic levels with specific resonances in the excited molecule.

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页码：4860 / 4863

页数：4

相关论文

共 29 条

[1] OPTICAL SELECTION IN DOUBLE-RESONANT 2-PHOTON PHOTODISSOCIATION - NEAR-THRESHOLD STATE-TO-STATE FRAGMENTATION DYNAMICS OF NO2 + 2H-UPSILON-] NO(X 2-PI-1/2, V = 0, J, LAMBDA) + O(1D) [J].

BIGIO, L ;

GRANT, ER .

JOURNAL OF PHYSICAL CHEMISTRY, 1985, 89 (26) :5855-5862

[2]

BLATT JM, 1952, THEORETICAL NUCLEAR

[3] TIME-RESOLVED STUDIES OF NO2 PHOTOINITIATED UNIMOLECULAR DECOMPOSITION - STEP-LIKE VARIATION OF KUNI (E) [J].

BRUCKER, GA ;

IONOV, SI ;

CHEN, Y ;

WITTIG, C .

CHEMICAL PHYSICS LETTERS, 1992, 194 (4-6) :301-308

[4] LASER-INDUCED GRATINGS IN FREE JETS .2. PHOTODISSOCIATION DYNAMICS VIA PHOTOFRAGMENT TRANSIENT GRATINGS [J].

BUTENHOFF, TJ ;

ROHLFING, EA .

JOURNAL OF CHEMICAL PHYSICS, 1993, 98 (07) :5469-5476

[5] ANALYSIS OF V1 + V3 BAND OF (NO2)-N(14)-O(16) [J].

DANA, V ;

MAILLARD, JP .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1978, 71 (1-3) :1-14

[6] LASER-INDUCED DISPERSED FLUORESCENCE-SPECTRA OF JET COOLED NO2 - THE COMPLETE SET OF VIBRATIONAL LEVELS UP TO 10000 CM-1 AND THE ONSET OF THE X2A1-A2B2 VIBRONIC INTERACTION [J].

DELON, A ;

JOST, R .

JOURNAL OF CHEMICAL PHYSICS, 1991, 95 (08) :5686-5700

[7]

DELON A, 1991, J CHEM PHYS, V95, P5700

[8] FLUCTUATIONS OF NUCLEAR CROSS SECTIONS IN THE CONTINUUM REGION [J].

ERICSON, T .

PHYSICAL REVIEW LETTERS, 1960, 5 (09) :430-431

[9] TRANSITION-STATES AND RATE CONSTANTS FOR UNIMOLECULAR REACTIONS [J].

GREEN, WH ;

MOORE, CB ;

POLIK, WF .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, 1992, 43 :591-626

[10]

GREEN WH, 1991, J CHEM PHYS, V96, P196