NEUTRAL SALT EFFECT IN THE POLYMERIZATION OF N-VINYLCARBAZOLE BY TRITYL CATION IN NITROBENZENE

被引：2

作者：

GONZALEZ, M

RODRIGUEZ, M

LEON, LM

机构：

[1] Departamento de Química Física, Facultad de Ciencias, Universidad del País Vasco (UPV/EHU), 48080 Bilbao

来源：

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY | 1995年 / A32卷 / 10期

关键词：

D O I：

10.1080/10601329508010021

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The polymerization of N-vinylcarbazole in the presence of the PhCH(2)(CH3)(3)N+SbF6- salt has been studied at different temperatures (293 and 308 K) in nitrobenzene. An increase in k(p) at high [salt]/[I](0) ratios has been observed which can be explained by the strong interactions of the nitrobenzene solvent with the monomer and the propagating species.

引用

页码：1773 / 1780

页数：8

共 9 条

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[2]

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[3]

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[8]

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[9]

Grubisic Z., Remp P., Benoit H., J. Polym. Sri., Part B, 5, 753, (1967)

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