SYNTHESIS OF A CHIRAL MONOSUBSTITUTED DERIVATIVE OF BIS(ETHYLENEDITHIO)TETRATHIAFULVALENE - REACTION OF THE CYCLIC SULFATE ESTER OF R,R-1,4-DIFLUOROBUTANE-2,3-DIOL WITH 2-THIOXO-1,3-DITHIOLE-4,5-DITHIOLATE

被引：38

作者：

OZTURK, T ^{[1
]}

RICE, CR ^{[1
]}

WALLIS, JD ^{[1
]}

机构：

[1] UNIV KENT,CHEM LAB,MAT RES CTR,CANTERBURY CT2 7NH,KENT,ENGLAND

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1995年 / 5卷 / 10期

关键词：

D O I：

10.1039/jm9950501553

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

2-Thioxo-1,3-dithiole-4 5-dithiolate reacts stereospecifically with the cyclic sulfate ester of R,R-1,4-difluorobutane-2,3-diol by two nucleophilic attacks, ring opening of the cyclic sulfate ester at carbon and displacement of the nearer fluorine atom, to form a derivative of the 1,3-dithiolo[4,5-b]-1,4-dithiin ring system. This product is converted in two steps into an analogue of bis(ethylenedithio)tetrathiafulvalene with a 2-fluoro-1-hydroxyethyl side-chain, a new substrate for the preparation of electroactive materials.

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页码：1553 / 1556

页数：4

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