REDISTRIBUTION EQUILIBRIA OF SILANIC HYDROGEN WITH CHLORINE ON METHYLSILICON MOIETIES

被引：19

作者：

MOEDRITZER, K

VANWAZER, JR

机构：

[1] Central Research Department, Monsanto Company, St. Louis, MO

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1968年 / 12卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)90899-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The scrambling equilibria of silanic hydrogen with chlorine atoms on various combinations of mono-, di-, and trimethylsilicon moieties have been determined by proton nuclear magnetic resonance. The data have been evaluated in terms of sets of equilibrium constants which show that at equilibrium, the exchangeable hydrogen atoms prefer to be with the silicon moiety bearing the least number of methyl groups. © 1968.

引用

页码：69 / +

页数：1

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[2]

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[3]

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[4]

DOLGOV BN, 1957, ZH OBSHCH KHIM+, V27, P2692