SN2 REACTIONS IN THE GAS-PHASE - TRANSITION-STATES FOR THE REACTION - CL- + RBR = CLR + BR-, WHERE R = CH3, C2H5, AND ISO-C3H7, FROM ABINITIO CALCULATIONS AND COMPARISON WITH EXPERIMENT - SOLVENT EFFECTS

被引:38
作者
HIRAO, K [1 ]
KEBARLE, P [1 ]
机构
[1] UNIV ALBERTA,DEPT CHEM,EDMONTON T6G 2G2,ALBERTA,CANADA
来源
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1989年 / 67卷 / 08期
关键词
D O I
10.1139/v89-192
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
引用
收藏
页码:1261 / 1267
页数:7
相关论文
共 40 条
[1]   HYDRATION OF HALIDE NEGATIVE IONS IN GAS PHASE .2. COMPARISON OF HYDRATION ENERGIES FOR ALKALI POSITIVE AND HALIDE NEGATIVE IONS [J].
ARSHADI, M ;
YAMDAGNI, R ;
KEBARLE, P .
JOURNAL OF PHYSICAL CHEMISTRY, 1970, 74 (07) :1475-&
[2]   INTERPRETATION OF CHARGE AND ENERGY CHANGES IN 2 NUCLEOPHILIC DISPLACEMENT REACTIONS [J].
BADER, RFW ;
DUKE, AJ ;
MESSER, RR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (23) :7715-7721
[3]   THE GAS-PHASE DISPLACEMENT REACTION OF CHLORIDE-ION WITH METHYL-CHLORIDE AS A FUNCTION OF KINETIC-ENERGY [J].
BARLOW, SE ;
VANDOREN, JM ;
BIERBAUM, VM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (21) :7240-7242
[4]   THE KINETICS OF CERTAIN IONIC EXCHANGE REACTIONS OF THE 4 METHYL HALIDES IN AQUEOUS SOLUTION [J].
BATHGATE, RH ;
MOELWYNHUGHES, EA .
JOURNAL OF THE CHEMICAL SOCIETY, 1959, (SEP-O) :2642-2648
[5]   MOLECULAR-ORBITAL DESCRIPTION OF SN2 REACTIONS AT SILICON CENTERS [J].
BAYBUTT, P .
MOLECULAR PHYSICS, 1975, 29 (02) :389-403
[6]   BRIDGING THE GAP BETWEEN THE GAS-PHASE AND SOLUTION - TRANSITION IN THE KINETICS OF NUCLEOPHILIC DISPLACEMENT-REACTIONS [J].
BOHME, DK ;
MACKAY, GI .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (04) :978-979
[7]   SN2 REACTIONS IN THE GAS-PHASE - TEMPERATURE-DEPENDENCE OF THE RATE CONSTANTS AND ENERGIES OF THE TRANSITION-STATES - COMPARISON WITH SOLUTION [J].
CALDWELL, G ;
MAGNERA, TF ;
KEBARLE, P .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (04) :959-966
[8]   ENERGY PROFILE FOR A NONCONCERTED SN2 REACTION IN SOLUTION [J].
CHANDRASEKHAR, J ;
JORGENSEN, WL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (10) :2974-2975
[9]  
CHANDRASEKHAR J, 1984, J AM CHEM SOC, V106, P3079
[10]  
CURTIS LA, 1973, CHEM PHYS, V71, P2703