MULTIPLE RADICAL ADDITIONS STARTING WITH IMINYL RADICALS DERIVED FROM SULFENYLIMINES

被引：34

作者：

BOIVIN, J ^{[1
]}

FOUQUET, E ^{[1
]}

ZARD, SZ ^{[1
]}

机构：

[1] ECOLE POLYTECH,CNRS,SYNTHESE ORGAN LAB,F-91128 PALAISEAU,FRANCE

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 25期

关键词：

D O I：

10.1016/S0040-4039(00)94438-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Iminyl radicals obtained by tri-n-butylstannane induced cleavage of S-phenyl sulphenylimines readily cyclise onto suitably located double bonds. The intermediate carbon centered radical can be trapped by a variety of electron-poor olefins thus providing an entry into synthetically useful pyrroline derivatives. © 1990.

引用

页码：3545 / 3548

页数：4

共 16 条

[1] BARTON DHR, 1985, TETRAHEDRON LETT, P1229
[2] BECKWITH ALJ, 1980, REARRANGEMENTS GROUN, V1
[3] CYCLIZATION OF IMINE RADICALS DERIVED FROM SULPHENYLIMINES - A SIMPLE ACCESS TO DELTA-1-PYRROLINES
BOIVIN, J
FOUQUET, E
ZARD, SZ
[J]. TETRAHEDRON LETTERS, 1990, 31 (01) : 85 - 88
[4] CYANOHYDRIDOBORATE ANION AS A SELECTIVE REDUCING AGENT
BORCH, RF
BERNSTEIN, MD
DURST, HD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (12) : 2897 - +
[5] THE CHEMISTRY OF SULFENAMIDES
CRAINE, L
RABAN, M
[J]. CHEMICAL REVIEWS, 1989, 89 (04) : 689 - 712
[6] THE DESIGN AND APPLICATION OF FREE-RADICAL CHAIN REACTIONS IN ORGANIC-SYNTHESIS .1.
CURRAN, DP
[J]. SYNTHESIS-STUTTGART, 1988, (06): : 417 - 439
[7] THE DESIGN AND APPLICATION OF FREE-RADICAL CHAIN REACTIONS IN ORGANIC-SYNTHESIS .2.
CURRAN, DP
[J]. SYNTHESIS-STUTTGART, 1988, (07): : 489 - 513
[8] AMINATION OF ALKENES
GASC, MB
LATTES, A
PERIE, JJ
[J]. TETRAHEDRON, 1983, 39 (05) : 703 - 731
[9] GIESE G, 1986, RADICALS ORGANIC SYN
[10] FREE-RADICAL CARBON-CARBON BOND FORMATION IN ORGANIC-SYNTHESIS
HART, DJ
[J]. SCIENCE, 1984, 223 (4639) : 883 - 887

← 1 2 →