SYNTHESIS AND PROPERTIES OF OLIGO-6-(2-THIENYL)PENTAFULVENES

被引：11

作者：

KAWASE, T ^{[1
]}

KURATA, H ^{[1
]}

MORIKAWA, T ^{[1
]}

ODA, M ^{[1
]}

机构：

[1] OSAKA UNIV,FAC SCI,DEPT CHEM,TOYONAKA,OSAKA 560,JAPAN

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 21期

关键词：

D O I：

10.1016/S0040-4039(00)79180-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oligo-6-(2-thienyl)pentafulvenes, synthesized up to a tetramer by application of a new pentafulvene synthesis, show considerably low reduction potentials to suggest ready formation of polyanions or polyanion radicals with oligoacetylene spines.

引用

页码：3449 / 3452

页数：4

共 14 条

[1]

BINGMANN H, 1979, TETRAHEDRON LETT, P4053

[2]

GARRATT PJ, 1988, AROMATICITY, P173

[3]

HAFNER K, 1973, TETRAHEDRON LETT, P5105

[4] REDUCTIVE COUPLING OF 6-DIMETHYLAMINOFULVENES FURNISHING 6,6'-BIFULVENYLS [J].

KAWASE, T ;

NISATO, N ;

ODA, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (16) :1145-1146

[5] SYNTHESIS OF 2-CYCLOPENTADIENYLIDENE-2H-THIAPYRAN BY NOVEL REDUCTIVE REARRANGEMENT OF A 6-THIENYLFULVENE [J].

KAWASE, T ;

FUJINO, S ;

ODA, M .

TETRAHEDRON LETTERS, 1991, 32 (29) :3499-3502

[6] TANDEM REACTIONS OF N,N-DIALKYLAMIDES WITH ORGANOLITHIUM COMPOUNDS AND CYCLOPENTADIENE - A NEW EFFICIENT SYNTHESIS OF PENTAFULVENES [J].

KURATA, H ;

EKINAKA, T ;

KAWASE, T ;

ODA, M .

TETRAHEDRON LETTERS, 1993, 34 (21) :3445-3448

[7]

KURATA H, 1991, CHEM EXPRESS, V6, P853

[8]

KURODA S, 1976, TETRAHEDRON LETT, P251

[9] SYNTHESIS OF 8,8'-BIHEPTAFULVENYL [J].

KURODA, S ;

ODA, M ;

KITAHARA, Y .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1973, 12 (01) :76-77

[10]

Lloyd D., 1984, NONBENZENOID CONJUGA

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