THE SYNTHESIS OF ALKOXYCARBONYL, CARBAMOYL AND ISOCYANATO COMPLEXES, FAC-M(CO)3(P-P)Z [M=MN, RE - P-P=DPPE, DPPP - Z=C(O)OME, C(O)OET, C(O)NHPRN, NCO] - THE SINGLE-CRYSTAL STRUCTURES OF FAC-MN(CO)3(DPPP)C(O)OET AND FAC-MN(CO)3(DPPE)NCO

被引：21

作者：

MANDAL, SK ^{[1
]}

HO, DM ^{[1
]}

ORCHIN, M ^{[1
]}

机构：

[1] UNIV CINCINNATI,DEPT CHEM,CINCINNATI,OH 45221

来源：

POLYHEDRON | 1992年 / 11卷 / 16期

关键词：

D O I：

10.1016/S0277-5387(00)83162-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compounds were prepared by the reaction of the cationic complex [M(CO)4(P-P)]+[BF4]- With the appropriate nucleophiles leading to fac-M(CO)3(P-P)Z [M = Mn, Re; P-P = dppe, dppp; Z = C(O)OMe, C(O)OEt, C(O)NHPrn, NCO] complexes. The X-ray structures of fac-Mn(CO)3(dppp)C(O)OEt and fac-Mn(CO)3(dppe)NCO are also reported.

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页码：2055 / 2063

页数：9

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