SELF-ASSEMBLY OF POLYANIONS AT A METAL CATION TEMPLATE - SYNTHESES AND STRUCTURES OF [(AG([18]ANES(6)))I-7](N) AND [AG([18]ANES(6))]I-3

被引：64

作者：

BLAKE, AJ

GOULD, RO

PARSONS, S

RADEK, C

SCHRODER, M

机构：

[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND

[2] UNIV EDINBURGH,DEPT CHEM,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 21期

关键词：

CROWN THIOETHERS; MACROCYCLES; POLYIODIDES; SELF ASSEMBLY; SILVER COMPOUNDS;

D O I：

10.1002/anie.199523741

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A distorted cubic lattice of I −7 ions, in whose cavities the complex cations [Ag([18]aneS6)]+ ([18]aneS6 = 1,4,7,10,13,16‐hexathiacyclooctadecane) are encapsulated, is formed in the synthesis of 1 (section of structure shown on the right). I− ions are positioned at the lattice points; one I2 molecule is located along each edge. The Ag+ ions function as a secondsphere template in the synthesis of the I −7 polyanion. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

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页码：2374 / 2376

页数：3

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