THE INFLUENCE OF ORGANIC-SOLVENTS ON AROMATIC ADSORPTION AT PLATINUM - ACETIC-ACID, ACETONE, ACETONITRILE, DIMETHYLACETAMIDE, DIMETHYLSULFOXIDE, SULFOLANE, AND TETRAHYDROFURAN

被引：13

作者：

SONG, D

SORIAGA, MP

HUBBARD, AT

机构：

[1] Univ of California, Santa Barbara,, CA, USA, Univ of California, Santa Barbara, CA, USA

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1987年 / 134卷 / 04期

关键词：

ELECTROCHEMISTRY; -; ELECTRODES; Platinum; HYDROCARBONS; Adsorption;

D O I：

10.1149/1.2100589

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The influence of nonaqueous solvents on the packing density and electrochemical reactivity of 2,2 prime ,5,5 prime ,-tetrahydroxybiphenyl (THBP) chemisorbed at smooth polycrystalline Pt electrodes has been studied using thin layer electrochemical techniques. The results provide revealing glimpses of the role played by oriented adsorbed intermediates and nonaqueous solvents in the stereospecificity of organic electrochemical reactions. In particular, the data appear to invalidate previous assumptions that the orientation of adsorbed aromatic intermediates is flat, regardless of solute concentration or nature of the solvent.

引用

页码：874 / 880

页数：7

共 28 条

[1]

ADAM NK, 1941, PHYSICS CHEM SURFACE

[2]

Baizer M.M., 1983, ORGANIC ELECTROCHEMI

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