BENZYL 2,3-O-ISOPROPYLIDENE-BETA-D-RIBO-1,4-PENTODIALDOFURANOSIDE AS A D-RIBOSE CHIRON FOR THE SYNTHESIS OF TERPENYL TETRAOLS AND AMINOTRIOLS

被引：13

作者：

DUVOLD, T

FRANCIS, GW

PAPAIOANNOU, D

机构：

[1] UNIV PATRAS,DEPT CHEM,GR-26500 PATRAI,GREECE

[2] UNIV BERGEN,DEPT CHEM,N-5007 BERGEN,NORWAY

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 18期

关键词：

D O I：

10.1016/0040-4039(95)00483-S

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Wittig condensation of title compound with a phosphorane derived from R -(+)-limonene followed by catalytic hydrogenation, provided a C-5 extended ribofuranose derivative, a model intermediate for the synthesis of terpenyl tetraols,via NaBH4 reduction, and terpenyl aminotriols via sequential pyridinium dichromate oxidation, ammonolysis and LiAlH4 reduction.

引用

页码：3153 / 3156

页数：4

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