THE CRYSTAL-STRUCTURE OF TBU2P-P=P(BR)TBU2

被引:15
作者
BORRMANN, H [1 ]
KOVACS, I [1 ]
FRITZ, G [1 ]
机构
[1] UNIV KARLSRUHE,INST ANORGAN CHEM,D-76128 KARLSRUHE,GERMANY
来源
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1994年 / 620卷 / 10期
关键词
CRYSTAL STRUCTURE OF TBU2P-P=P(BR)TBU2;
D O I
10.1002/zaac.19946201026
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
tBu2P-P=P(Br)tBu2 1 crystallizes in the monoclinic space group P2(1)/c with a = 2888.9(3), b = 972.16(10), c = 1534.04(14) pm, beta = 105.129(8)-degrees and 8 formula units in the unit cell. The two independent P3-units in 1 form angles of 105.77-degrees or 105.98-degrees, resp. One P-P distance (220,4 pm) corresponds to a single bond, the other one (207.9 pm) to a double bond.
引用
收藏
页码:1818 / 1820
页数:3
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