A FUNDAMENTAL-STUDY ON CONVENTIONAL PYROLYSIS OF A REFUSE-DERIVED FUEL

被引:59
作者
COZZANI, V [1 ]
NICOLELLA, C [1 ]
PETARCA, L [1 ]
ROVATTI, M [1 ]
TOGNOTTI, L [1 ]
机构
[1] UNIV GENOA,IST SCI & TECNOL INGN CHIM,I-16145 GENOA,ITALY
关键词
D O I
10.1021/ie00045a010
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The pyrolysis behavior of a refuse-derived fuel (RDF) under heating conditions typical of conventional pyrolysis processes was investigated. Thermogravimetric analysis and differential scanning calorimetry were performed on RDF and on some materials which have been considered ''key components'' of the thermal degradation of RDF. The product fractions obtained by RDF pyrolysis runs in a laboratory-scale fixed bed reactor, at temperatures between 500 and 900 degrees C, were identified and characterized by different experimental techniques, including gas chromatographic analysis of gaseous products, ultimate analysis, scanning electron microscopy and internal surface area measurements of char. Gas, tar, and char global yields were determined as a function of reactor temperature. The influence of gas-phase secondary tar-cracking reactions on final gas composition was investigated. Overall kinetic parameters obtained by a simple kinetic model are compared to literature data.
引用
收藏
页码:2006 / 2020
页数:15
相关论文
共 48 条
[1]   LOW-PRESSURE PYROLYSIS OF NEWSPRINT PRODUCT FORMATION [J].
AGRAWAL, RK ;
GANDHI, F ;
MCCLUSKEY, RJ .
JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1984, 6 (03) :325-338
[2]  
ANTAL JM, 1983, IND ENG CHEM PROD RD, V22, P166
[3]  
Antal MJ, 1985, ADV SOLAR ENERGY, P175, DOI [10.1007/978-1-4613-9951-3_4, DOI 10.1007/978-1-4613-9951-3_4]
[4]  
BERGULI G, 1994, THESIS U STUDI GENOV
[5]   KINETICS OF THERMAL-DECOMPOSITION OF CELLULOSE .1. INFLUENCE OF EXPERIMENTAL CONDITIONS [J].
BILBAO, R ;
ARAUZO, J ;
MILLERA, A .
THERMOCHIMICA ACTA, 1987, 120 :121-131
[6]   KINETICS OF WEIGHT-LOSS BY THERMAL-DECOMPOSITION OF XYLAN AND LIGNIN - INFLUENCE OF EXPERIMENTAL CONDITIONS [J].
BILBAO, R ;
MILLERA, A ;
ARAUZO, J .
THERMOCHIMICA ACTA, 1989, 143 :137-148
[7]   KINETIC-STUDY ON BIOMASS GASIFICATION (A 1991 ISES SOLAR WORLD CONGRESS HONORS PAPER) [J].
BINGYAN, X ;
CHUANGZHI, W ;
ZHENGFEN, L ;
GUANG, ZX .
SOLAR ENERGY, 1992, 49 (03) :199-204
[8]   PRODUCT YIELDS AND KINETICS FROM THE VAPOR-PHASE CRACKING OF WOOD PYROLYSIS TARS [J].
BOROSON, ML ;
HOWARD, JB ;
LONGWELL, JP ;
PETERS, WA .
AICHE JOURNAL, 1989, 35 (01) :120-128
[9]   EUROPEAN-EXPERIENCE IN THE PYROLYSIS AND GASIFICATION OF SOLID-WASTES [J].
BUEKENS, AG ;
SCHOETERS, JG .
CONSERVATION & RECYCLING, 1986, 9 (03) :253-269
[10]  
CAPART R, 1986, ENERGY BIOMASS, P842