CATALYSIS OF PD(II)-CATALYZED ACETALIZATION OF ALKENES WITH DIOLS

被引：42

作者：

HOSOKAWA, T

ATAKA, Y

MURAHASHI, SI

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1990年 / 63卷 / 01期

关键词：

D O I：

10.1246/bcsj.63.166

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alkenes bearing electron-withdrawing substituents are catalytically acetalized with 1,3-propanediol only by the use of PdCl2(MeCN)2 catalyst under O2 atmosphere. When a combination of BiCl3 and LiCl is used as co-catalyst, the acetalization proceeds effectively. These results indicate that a hydroperoxopalladium(II) species is most likely an active catalyst in the present reaction.

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页码：166 / 169

页数：4

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