A MODEL FOR THE ATTACK OF A NUCLEOPHILE ON A NITRILE GROUP - THE X-RAY CRYSTAL-STRUCTURE OF 2,2'-BIPYRIDINE-3,3'-DICARBONITRILE

被引：27

作者：

BAXTER, PNW

CONNOR, JA

POVEY, DC

WALLIS, JD

机构：

[1] UNIV KENT,CHEM LAB,CANTERBURY CT2 7NH,KENT,ENGLAND

[2] UNIV SURREY,DEPT CHEM,GUILDFORD GU2 5XH,SURREY,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 16期

关键词：

D O I：

10.1039/c39910001135

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

From analysis of the geometry of the attractive intramolecular interactions between the pyridine N atoms and the nitrile C atoms in title compound 2 it is proposed that the most favoured direction of approach of a nucleophile to an sp C(=N) makes an angle of at least 108-degrees to the triple bond.

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页码：1135 / 1137

页数：3

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