CATION EFFECTS IN THE OXIDATIVE DEHYDROGENATION OF METHANE ON SULFATES

被引：15

作者：

SUGIYAMA, S

MOFFAT, JB

机构：

[1] UNIV WATERLOO,DEPT CHEM,WATERLOO N2L 3G1,ONTARIO,CANADA

[2] UNIV WATERLOO,GUELPH WATERLOO CTR GRAD WORK CHEM,WATERLOO N2L 3G1,ONTARIO,CANADA

来源：

CATALYSIS LETTERS | 1992年 / 13卷 / 1-2期

关键词：

METHANE; CONVERSION; OXIDATIVE DEHYDROGENATION; CATIONS; SULFATES;

D O I：

10.1007/BF00770957

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The oxidative coupling of methane has been studied on Mg, Ca, Sr and Ba sulphate. The conversions and selectivities are found to be dependent on the nature of the cation and to be approximately correlated with their electronegativities, thus implying that the C-H bond scission in CH4, at least with these catalysts, is heterolytic, is rate determining, and further, that the formation of C2+ hydrocarbons is dependent, among other factors, on the concentration of methyl radicals.

引用

页码：143 / 152

页数：10