CHARACTERIZATION OF THE INTERACTION BETWEEN POLY(PYRROLE) FILMS AND METHANOL VAPOR

被引：60

作者：

TOPART, P ^{[1
]}

JOSOWICZ, M ^{[1
]}

机构：

[1] UNIV BUNDESWEHR,FAK ELEKTROTECH,INST PHYS,WERNER HEISENBERG WEG 39,W-8014 MUNICH,GERMANY

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 19期

关键词：

D O I：

10.1021/j100198a059

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A combination of mass, optical spectroscopy, and work function measurements has been used to study the interaction of methanol vapor with poly(pyrrole) thin films. The steady-state measurements carried out in this study open the way for qualitative and quantitative evaluation of the charge-transfer and sorption interactions of organic vapors with the ''network solids''. It is shown that the chemical nature of the dopant anion incorporated in the poly(pyrrole) matrix strongly influences the reversible doping by the vapor.

引用

页码：7824 / 7830

页数：7

共 25 条

[1]

ATKINS PW, 1990, PHYSICAL CHEM, P888

[2] A QUARTZ MICROBALANCE STUDY OF THE ELECTROSYNTHESIS OF POLYPYRROLE [J].

BAKER, CK ;

REYNOLDS, JR .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 251 (02) :307-322

[3] SURFACE STATES AND RECTIFICATION AT A METAL SEMI-CONDUCTOR CONTACT [J].

BARDEEN, J .

PHYSICAL REVIEW, 1947, 71 (10) :717-727

[4] WORK FUNCTION AND SPECTROSCOPIC STUDIES OF INTERACTIONS BETWEEN CONDUCTING POLYMERS AND ORGANIC VAPORS [J].

BLACKWOOD, D ;

JOSOWICZ, M .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (01) :493-502

[5] POLARONS AND BIPOLARONS IN POLYPYRROLE - EVOLUTION OF THE BAND-STRUCTURE AND OPTICAL-SPECTRUM UPON DOPING [J].

BREDAS, JL ;

SCOTT, JC ;

YAKUSHI, K ;

STREET, GB .

PHYSICAL REVIEW B, 1984, 30 (02) :1023-1025

[6]

BUHKS E, 1983, J CHEM PHYS, V11, P5976

[7]

Buttry D.A., 1991, ELECTROANALYTICAL CH, V17, P1

[8] UNDERPOTENTIAL METAL-DEPOSITION ON GOLD, MONITORED INSITU WITH A QUARTZ MICROBALANCE [J].

DEAKIN, MR ;

MELROY, O .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 239 (1-2) :321-331

[9] MECHANICAL-PROPERTIES OF ELECTROCHEMICALLY PREPARED POLYPYRROLE FILMS [J].

DIAZ, AF ;

HALL, B .

IBM JOURNAL OF RESEARCH AND DEVELOPMENT, 1983, 27 (04) :342-347

[10]

DIAZ AF, 1986, HDB CONDUCTING POLYM, V1, P81

← 1 2 3 →