ROTATIONAL RELAXATION IN A FREE EXPANSION OF HCL

被引：9

作者：

RUDICH, Y

GORDON, RJ

NIKITIN, EE

NAAMAN, R

机构：

[1] UNIV ILLINOIS,DEPT CHEM,CHICAGO,IL 60680

[2] TECHNION ISRAEL INST TECHNOL,DEPT CHEM,HAIFA,ISRAEL

来源：

JOURNAL OF CHEMICAL PHYSICS | 1992年 / 96卷 / 06期

关键词：

D O I：

10.1063/1.462833

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The rotational relaxation of HCl in a free jet expansion was studied in a pump-and-probe experiment using infrared laser excitation and resonant multiphoton ionization detection. Rate constants were determined for various J to J' energy transfer processes in the vibrationally excited molecule. There is a strong indication that the rotational energy transfer occurs via a near-resonant dipole-dipole interaction between vibrationally excited and vibrationally cold HCl molecules.

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收藏

页码：4423 / 4428

页数：6

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