STRUCTURE-ACTIVITY AND STRUCTURE-SELECTIVITY CORRELATIONS IN METALLOCENE-BASED CATALYSTS FOR ALPHA-OLEFIN POLYMERIZATION

被引：65

作者：

BURGER, P ^{[1
]}

HORTMANN, K ^{[1
]}

BRINTZINGER, HH ^{[1
]}

机构：

[1] UNIV CONSTANCE,FAK CHEM,POSTFACH 5560,W-7750 CONSTANCE,GERMANY

来源：

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1993年 / 66卷

关键词：

D O I：

10.1002/masy.19930660113

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Zirconocene complexes carrying substituents at various positions of their ring-bridged ligand frameworks were studied as catalysts for methylalumoxane-activated propene polymerization. Effects of different substitution patterns on catalyst activities and on chain lengths and stereo- and regio-regularities of the polymers produced are correlated with geometrical features of the complexes, e.g. with parameters describing their structural rigidity or the aperture and obliquity of their coordination gaps.

引用

页码：127 / 139

页数：13

共 19 条

[1] SYNTHESIS, STRUCTURAL CHARACTERIZATION, AND ELECTROCHEMISTRY OF [1]METALLOCENOPHANE COMPLEXES, [SI(ALKYL)2(C5H4)2]TICL2,[SI(ALKYL)2(C5H4)2]ZRCL2
BAJGUR, CS
TIKKANEN, WR
PETERSEN, JL
[J]. INORGANIC CHEMISTRY, 1985, 24 (16) : 2539 - 2546
[2] ANSA-METALLOCENE DERIVATIVES .24. DEVIATIONS FROM C2-AXIAL SYMMETRY IN ETHANO-BRIDGED AND ETHENO-BRIDGED TITANOCENE COMPLEXES - INVESTIGATION OF ANSA-METALLOCENE CONFORMATIONS
BURGER, P
DIEBOLD, J
GUTMANN, S
HUND, HU
BRINTZINGER, HH
[J]. ORGANOMETALLICS, 1992, 11 (03) : 1319 - 1327
[3] GENERAL SYNTHETIC ROUTES TO CHIRAL, ETHYLENE-BRIDGED ANSA-TITANOCENE DICHLORIDES
COLLINS, S
HONG, YP
TAYLOR, NJ
[J]. ORGANOMETALLICS, 1990, 9 (10) : 2695 - 2703
[4] CORRADINI P, 1988, GAZZ CHIM ITAL, V118, P173
[5] CORRADINI P, 1991, POLYMER, V32, P1329
[6] MICROSTRUCTURE OF ISOTACTIC POLYPROPYLENE PREPARED WITH HOMOGENEOUS CATALYSIS - STEREOREGULARITY, REGIOREGULARITY, AND 1,3-INSERTION
GRASSI, A
ZAMBELLI, A
RESCONI, L
ALBIZZATI, E
MAZZOCCHI, R
[J]. MACROMOLECULES, 1988, 21 (03) : 617 - 622
[7] GRASSI A, 1988, GAZZ CHIM ITAL, V118, P539
[8] ANSA-METALLOCENE DERIVATIVES .16. CHIRAL TITANOCENE AND ZIRCONOCENE DERIVATIVES WITH SYMMETRICALLY SUBSTITUTED, TETRAMETHYLETHANEDIYL-BRIDGED LIGAND FRAMEWORKS - CRYSTAL-STRUCTURES OF REPRESENTATIVE EXAMPLES
GUTMANN, S
BURGER, P
HUND, HU
HOFMANN, J
BRINTZINGER, HH
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 369 (03) : 343 - 357
[9] HORTMANN K, 1992, NEW J CHEM, V16, P51
[10] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF GROUP-4 ANSA-METALLOCENE COMPLEXES CONTAINING A 1-SILA-3-METALLACYCLOBUTANE RING
KABISATPATHY, A
BAJGUR, CS
REDDY, KP
PETERSEN, JL
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 364 (1-2) : 105 - 117

← 1 2 →