A NEW ALPHA-ALPHA'-DIIODINATION OF KETONES USING IODINE-CERIUM(IV) AMMONIUM-NITRATE

被引：19

作者：

HORIUCHI, CA

TAKAHASHI, E

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 01期

关键词：

D O I：

10.1246/bcsj.67.271

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The direct iodination of some ketones using iodine-cerium(IV) ammonium nitrate in acetic acid or acetonitrile gave the corresponding alpha alpha'-diiodoketones in good yield. In the case of cyclododecanone (4), 3-pentanone (5), and 5-nonanone (6), cis- (mese-) compounds [2,12-diiodocyclododecanone (12), 2,4-diiodo-3-pentanone (13), and 4,6-diiodo-5-nonanone (14)] were obtained preferentially.

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页码：271 / 273

页数：3

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