DIHYDROXYCARBENE HO-C-OH - ITS FORMATION IN THE GAS-PHASE BY ELECTRON-TRANSFER TO ITS RADICAL-CATION

被引：39

作者：

BURGERS, PC ^{[1
]}

MCGIBBON, GA ^{[1
]}

TERLOUW, JK ^{[1
]}

机构：

[1] MCMASTER UNIV,DEPT CHEM,HAMILTON L8S 4M1,ONTARIO,CANADA

来源：

CHEMICAL PHYSICS LETTERS | 1994年 / 224卷 / 5-6期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/0009-2614(94)00569-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Dihydroxycarbene, HO-C-OH, has been generated and identified in the gas-phase by electron capture of the corresponding radical cations in neutralization-reionization experiments. The precursor ions were made by dissociative ionization of dihydroxyfumaric acid and their structure was established on the basis of collision experiments. The experimental results are consistent with previously published ab initio calculations.

引用

页码：539 / 543

页数：5

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