KINETIC-STUDIES OF THE ELECTROCHEMICAL REACTION BETWEEN LITHIUM AND PHTHALOCYANINE .2. REDUCTION REACTION-MECHANISM

被引：4

作者：

DJELLAB, H

DALARD, F

DEROO, D

ARMAND, MB

机构：

[1] CNRS, Lab d'Energetique, Electrochimique, St. Martin d'Heres,, Fr, CNRS, Lab d'Energetique Electrochimique, St. Martin d'Heres, Fr

来源：

JOURNAL OF POWER SOURCES | 1985年 / 16卷 / 01期

关键词：

ELECTROCHEMISTRY;

D O I：

10.1016/0378-7753(85)80002-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reduction reaction mechanism of metal-free phthalocyanine (H//2Pc) in the presence of alkali cations was studied. The chemical lithiation was obtained by reaction with n-butyl lithium. The chromatographic analysis of the chemical products revealed both octane and butane. The presence of butane as a co-product could be due to the hydrogen substitution reaction with n-butyl lithium. The present work suggests that the cathodic reduction involves both lithium intercalation and phthalocyanine anion dissolution into the polymer electrolyte.

引用

页码：45 / 51

页数：7

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