VISCOSITY AND FLOW PROPERTIES OF CONCENTRATED-SOLUTIONS OF CHITOSAN WITH DIFFERENT DEGREES OF DEACETYLATION

被引:78
作者
WANG, W
XU, DS
机构
[1] Polymer Physics Laboratory, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun
关键词
CHITOSAN; DEGREE OF DEACETYLATION; VISCOSITY; FLOW PROPERTIES;
D O I
10.1016/0141-8130(94)90042-6
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The effects of the degree of deacetylation (DD) on the viscosity and flow behaviour of concentrated solutions of chitosan were investigated using 0.2 M CH3COOH and 0.2 M CH3COOH/0.1 M CH3COONa aqueous solutions as solvents. The results indicated that the viscosity and flow properties of the solutions differed with the DD of chitosan. The solution viscosities and the non-Newtonian flow properties as well as the flow activation energies E(gamma) increased with the increasing DD of chitosan. However, the additional salt decreased the viscosities and the non-Newtonian flow properties of the solutions of chitosan, but did not change the flow activation energies E(gamma) of the solutions.
引用
收藏
页码:149 / 152
页数:4
相关论文
共 12 条
[2]  
[Anonymous], 2013, CHITIN
[3]   PREPARATION AND CHARACTERIZATION OF FULLY DEACETYLATED CHITOSAN [J].
DOMARD, A ;
RINAUDO, M .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 1983, 5 (01) :49-52
[4]   DILUTE-SOLUTION BEHAVIOR OF A CATIONIC POLY-ELECTROLYTE [J].
KIENZLESTERZER, C ;
RODRIGUEZSANCHEZ, D ;
RHA, C .
JOURNAL OF APPLIED POLYMER SCIENCE, 1982, 27 (11) :4467-4470
[5]  
LEE VF, 1975, DISS ABSTR INT B, V35, P3275
[6]   DETERMINATION OF THE VISCOMETRIC CONSTANTS FOR CHITOSAN [J].
ROBERTS, GAF ;
DOMSZY, JG .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 1982, 4 (06) :374-377
[7]  
SMIDSROD O, 1959, 4TH INT C CHIT CHIT, V36, P295
[8]   LIGHT SCATTERING AND VISCOSITIES OF CHITOSAN IN AQUEOUS SOLUTIONS OF SODIUM CHLORIDE [J].
VANDUIN, PJ ;
HERMANS, JJ .
JOURNAL OF POLYMER SCIENCE, 1959, 36 (130) :295-304
[9]  
WANG W, 1991, MAKROMOL CHEM-RAPID, V12, P559
[10]  
Wang W., 1992, ACTA POLYM SIN, V2, P202