SYNTHESIS AND CHARACTERIZATION OF A HIGH-MOLECULAR-WEIGHT STIFF DENDRIMER

被引：103

作者：

XU, ZF ^{[1
]}

MOORE, JS ^{[1
]}

机构：

[1] UNIV MICHIGAN,WILLARD H DOW LABS,ANN ARBOR,MI 48109

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 02期

关键词：

D O I：

10.1002/anie.199302461

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

94 Monomeric units make up 1, the largest pure hydrocarbon yet characterized (C1134H1146). The compound which, thanks to its di-tert-butylphenyl groups, is extremely soluble in pentane (!) was obtained from the monodendron precursor and triiodobenzene with a Pd catalyst in 37% yield. Elemental analysis and H-1 NMR spectra clearly prove its structure. The benzene rings are shown as filled circles; the lines in between represent C=C units.

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页码：246 / 248

页数：3

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