A TOTAL SYNTHESIS OF THE SESQUITERPENE QUINONE METACHROMIN-A

被引：26

作者：

ALMEIDA, WP

CORREIA, CRD

机构：

[1] UNIV FED RIO DE JANEIRO,INST QUIM,BR-21945970 RIO JANEIRO,BRAZIL

[2] UNIV ESTADUAL CAMPINAS,INST QUIM,BR-13081970 CAMPINAS,SP,BRAZIL

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 09期

关键词：

D O I：

10.1016/S0040-4039(00)76220-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first total synthesis of the marine natural product metachromin A was accomplished through a convergent synthesis amenable to the preparation of synthetic analogues. The main features of this synthesis are the introduction of the oxygenation at C-17 employing a Thiele acetoxylation reaction and a stereoselective Horner-Wadsworth-Emmons coupling

引用

页码：1367 / 1370

页数：4

共 23 条

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[Anonymous], 1977, WILEY ONLINE LIB

[2]

BACHMANN WE, 1942, ORG REACTIONS, V1, P38, DOI DOI 10.1002/0471264180.OR001.02

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