IMPROVED CAPACITY RETENTION IN RECHARGEABLE 4V LITHIUM LITHIUM MANGANESE OXIDE (SPINEL) CELLS

被引：1404

作者：

GUMMOW, RJ ^{[1
]}

DEKOCK, A ^{[1
]}

THACKERAY, MM ^{[1
]}

机构：

[1] CSIR, DIV MAT SCI & TECHNOL, PRETORIA 0001, SOUTH AFRICA

来源：

SOLID STATE IONICS | 1994年 / 69卷 / 01期

关键词：

D O I：

10.1016/0167-2738(94)90450-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The rechargeable capacity of 4 V LixMn2O4 spinel cathodes (0 < x less-than-or-equal-to 1) has been improved by modifying the composition of the spinel electrode. Stable rechargeable capacities in excess of 100 mAh/g in flooded-electrolyte lithium cells can be achieved if LiMn2O4 is doped with mono- or multivalent cations (e.g. Li+, Mg2+, Zn2+) or, alternatively, with additional oxygen to increase the average manganese-ion oxidation state marginally above 3.5.

引用

页码：59 / 67

页数：9

共 14 条

[1] THE SWING SYSTEM, A NONAQUEOUS RECHARGEABLE CARBON METAL-OXIDE CELL
BITTIHN, R
HERR, R
HOGE, D
[J]. JOURNAL OF POWER SOURCES, 1993, 43 (1-3) : 223 - 231
[2] DEFECT SPINELS IN THE SYSTEM LI2O.YMNO2 (Y-GREATER-THAN-2.5) - A NEUTRON-DIFFRACTION STUDY AND ELECTROCHEMICAL CHARACTERIZATION OF LI2MN4O9
DEKOCK, A
ROSSOUW, MH
DEPICCIOTTO, LA
THACKERAY, MM
DAVID, WIF
IBBERSON, RM
[J]. MATERIALS RESEARCH BULLETIN, 1990, 25 (05) : 657 - 664
[3] GUMMOW RJ, 1993, THESIS U CAPE TOWN
[4] LI METAL-FREE RECHARGEABLE LIMN2O4/CARBON CELLS - THEIR UNDERSTANDING AND OPTIMIZATION
GUYOMARD, D
TARASCON, JM
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1992, 139 (04) : 937 - 948
[5] RECHARGEABLE LI1+XMN2O4/CARBON CELLS WITH A NEW ELECTROLYTE-COMPOSITION - POTENTIOSTATIC STUDIES AND APPLICATION TO PRACTICAL CELLS
GUYOMARD, D
TARASCON, JM
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (11) : 3071 - 3081
[6] PREPARATION OF A NEW CRYSTAL FORM OF MANGANESE-DIOXIDE - LAMBDA-MNO2
HUNTER, JC
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 1981, 39 (02) : 142 - 147
[7] RECHARGEABLE LITHIUM BATTERY WITH SPINEL-RELATED MNO2 .2. OPTIMIZATION OF THE LIMN2O4 SYNTHESIS CONDITIONS
MOMCHILOV, A
MANEV, V
NASSALEVSKA, A
KOZAWA, A
[J]. JOURNAL OF POWER SOURCES, 1993, 41 (03) : 305 - 314
[8] ELECTROCHEMISTRY OF MANGANESE-DIOXIDE IN LITHIUM NONAQUEOUS CELL .3. X-RAY DIFFRACTIONAL STUDY ON THE REDUCTION OF SPINEL-RELATED MANGANESE-DIOXIDE
OHZUKU, T
KITAGAWA, M
HIRAI, T
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (03) : 769 - 775
[9] THE SPINEL PHASE OF LIMN2O4 AS A CATHODE IN SECONDARY LITHIUM CELLS
TARASCON, JM
WANG, E
SHOKOOHI, FK
MCKINNON, WR
COLSON, S
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1991, 138 (10) : 2859 - 2864
[10] THE LI1+XMN2O4/C ROCKING-CHAIR SYSTEM - A REVIEW
TARASCON, JM
GUYOMARD, D
[J]. ELECTROCHIMICA ACTA, 1993, 38 (09) : 1221 - 1231

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