TITRATION OF C-60 - A METHOD FOR THE SYNTHESIS OF ORGANOFULLERENES

被引：214

作者：

HIRSCH, A ^{[1
]}

SOI, A ^{[1
]}

KARFUNKEL, HR ^{[1
]}

机构：

[1] CIBA GEIGY AG,CH-4002 BASEL,SWITZERLAND

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 06期

关键词：

D O I：

10.1002/anie.199207661

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Isomerically pure monoadducts of C60 such as C60HEt (only the front aspect shown on the right) were obtained from the titration of C60 with alkyllithium or Grignard reagents, followed by protonation. The nucleophile adds to the fullerene framework at a double bond between two six-rings, as was confirmed by the results of AM1 calculations. This method may provide access to organofullerenes C60RR' and C60R2.

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页码：766 / 768

页数：3

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