REACTION OF PERFLUOROALKANESULFINATES WITH ALLYL AND PROPARGYL HALIDES - A CONVENIENT SYNTHESIS OF 3-(PERFLUOROALKYL)PROP-1-ENES AND 3-(PERFLUOROALKYL)ALLENES

被引：35

作者：

HU, CM

QING, FL

HUANG, WY

机构：

[1] Shanghai Institute of Organic Chemistry, Academia Sinica, Shanghai 200032

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 08期

关键词：

D O I：

10.1021/jo00008a041

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of perfluoroalkanesulfinates, R(f)CF2SO2Na, with allyl and propargyl halides, in the presence of (NH4)2S2O8, gave 3-(perfluoroalkyl)prop-1-enes (R(f)CH2CH = CH2) and 3-(perfluoroalkyl)allenes (R(f)CH = C = CH2), respectively, in good yield. Evidence is presented for a radical addition-elimination mechanism for the reaction. The reaction represents a synthetically viable and convenient route to such compounds.

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页码：2801 / 2804

页数：4

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