LIQUID-LIQUID-EXTRACTION OF TRANSITION AND ALKALI-METAL CATIONS BY A NEW CALIXARENE - DIPHENYLPHOSPHINO CALIX[4]ARENE METHYL-ETHER

被引：52

作者：

HAMADA, F ^{[1
]}

FUKUGAKI, T ^{[1
]}

MURAI, K ^{[1
]}

ORR, GW ^{[1
]}

ATWOOD, JL ^{[1
]}

机构：

[1] UNIV ALABAMA,DEPT CHEM,TUSCALOOSA,AL 35487

来源：

JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY | 1991年 / 10卷 / 01期

关键词：

CALIX[4]ARENE; SOLVENT EXTRACTION; ALKALI METAL ION; TRANSITION METAL ION;

D O I：

10.1007/BF01041639

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The liquid-liquid extraction of various metal ions by a diphenylphospino calix[4]arene (1) using picrate counter ion has been studied and compared with those of p-teri-butyl-calix[4]arene methyl ether (2) and triphenylphosphine (3). The calixarene 1 shows strong binding ability to almost all metal cations examined, but calixarene 2 shows little ability to extract any of them. Based on the continuous variation method, calixarene 1 formed 1:2 complexes with copper(II) ion.

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页码：57 / 61

页数：5

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