REACTIONS OF 2-HALOVINYL ARYL SULFOXIDES WITH ORGANOMETALLIC REAGENTS

被引：37

作者：

CARDELLICCHIO, C ^{[1
]}

FIANDANESE, V ^{[1
]}

NASO, F ^{[1
]}

机构：

[1] UNIV BARI,DIPARTIMENTO CHIM,CNR,CTR STUDIO METODOL INNOVAT SINTESI ORGAN,VIA AMENDOLA 173,I-70126 BARI,ITALY

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1992年 / 57卷 / 06期

关键词：

D O I：

10.1021/jo00032a023

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(E)- and (Z)-2-halovinyl aryl sulfoxides 1-4 were subjected to reactions with organocopper, organomagnesium, or organolithium reagents. The organometallic reagents gave different products: diorganocuprates led to formation of carbon-carbon bond, with production of alkenyl sulfoxides 5-10, whereas formation of carbon-sulfur bond and production of diaryl or aryl alkyl sulfoxides 11-13 were observed in the reaction with the other organometallics. Possible mechanisms for the two observed processes are briefly discussed.

引用

页码：1718 / 1722

页数：5

共 43 条

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ANDERSEN KK, 1988, CHEM SULFONES SULFOX, pCH3

[2]

Angeletti E., 1957, GAZZ CHIM ITAL, V87, P1086

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