SYNTHESIS OF ORGANOPHOSPHORUS COMPOUNDS VIA SILYL ESTERS OF PHOSPHORUS-ACIDS

被引：109

作者：

AFARINKIA, K ^{[1
]}

REES, CW ^{[1
]}

CADOGAN, JIG ^{[1
]}

机构：

[1] BP INT LTD,SUNBURY RES CTR,SUNBURY TW16 7LN,MIDDX,ENGLAND

来源：

TETRAHEDRON | 1990年 / 46卷 / 20期

关键词：

D O I：

10.1016/S0040-4020(01)87899-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The addition of trimethylsilyloxy phosphorus (III)derivatives generated in situ to imines at room temperature provides a mild selective and high yielding route to α-aminoalkylphosphorate and α-aminoalkylphenylphosphinate esters. Isocyanates and carbodiimides react similarly to give phosphonoureas and phosphonoguarnidines respectively aldehydes and ketones are much less reactive and cyanides are inert. © 1990.

引用

页码：7175 / 7196

页数：22

共 33 条

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