TRISPYRAZOLYLBORATE DEGRADATION AND THE CRYSTAL-STRUCTURE OF [MO(NO)(CO)2(HB(OPRI)(3-PRI-5-MEC3HN2)2)]

被引：18

作者：

CANO, M

HERAS, JV

SANTAMARIA, E

PINILLA, E

MONGE, A

JONES, CJ

MCCLEVERTY, JA

机构：

[1] UNIV BIRMINGHAM,SCH CHEM,BIRMINGHAM B15 2TT,W MIDLANDS,ENGLAND

[2] UNIV COMPLUTENSE,FAC CIENCIAS QUIM,DEPT QUIM INORGAN,E-28040 MADRID,SPAIN

[3] UNIV COMPLUTENSE,FAC CIENCIAS QUIM,DIFFRAC RAYOS X LAB,CSIC,INST CIENCIAS MAT D,E-28040 MADRID,SPAIN

[4] UNIV BRISTOL,SCH CHEM,BRISTOL BS8 1TS,AVON,ENGLAND

来源：

POLYHEDRON | 1993年 / 12卷 / 13期

关键词：

D O I：

10.1016/S0277-5387(00)87084-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex [Mo(NO){HB(OPr(i))(3-Pr(i)-5-MeC3HN2)2}(CO)2] has been isolated from one attempt to prepare [Mo(NO){HB(3-Pr(i)-5-MeC3HN2)3}(CO)2]; a crystal structure shows the presence of an isopropoxide group with the alkoxy oxygen bound to the boron and molybdenum atoms [Mo-O = 2.225(5) angstrom].

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页码：1711 / 1714

页数：4

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