THERMAL-PROPERTIES OF FE-FULLERENE SYSTEMS - IS REACTION C-60+FE-]FE-AT-C-60 IN SOLID FULLERITE POSSIBLE

被引：10

作者：

BYSZEWSKI, P ^{[1
]}

KOWALSKA, E ^{[1
]}

DIDUSZKO, R ^{[1
]}

机构：

[1] POLISH ACAD SCI,INST PHYS,PL-02628 WARSAW,POLAND

来源：

JOURNAL OF THERMAL ANALYSIS | 1995年 / 45卷 / 05期

关键词：

FULLERENE;

D O I：

10.1007/BF02547495

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Iron in the fullerite lattice binds fullerenes in a sandwich type C60FeC60 complexes. At the concentration C60Fe2 it crystallizes in the monoclinic lattice. The structure is thermally unstable, with the energy release of 606 kJ . mol(-1) it returns to fcc lattice. Two possible sites in the reconstructed fee lattice are discussed, Fe bond to C-60 and Fe inside the C-60 cage.

引用

页码：1205 / 1210

页数：6

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