NOVEL GENERATION OF AZOMETHINE YLIDE FROM N-(ALPHA-SILYLBENZYL)AMIDE BY SILICON SHIFT - AN EQUIVALENT OF NITRILE YLIDE

被引：37

作者：

OHNO, M ^{[1
]}

KOMATSU, M ^{[1
]}

MIYATA, H ^{[1
]}

OHSHIRO, Y ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,YAMADAOKA 2-1,SUITA,OSAKA 565,JAPAN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 41期

关键词：

D O I：

10.1016/S0040-4039(00)93562-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Azomethine ylides were generated from N-(alpha-silylbenzyl)amides by thermal silicon shift to the oxygen and trapped with dipolarophiles to give the same products as those from the corresponding nitrile ylides via elimination of silanol.

引用

页码：5813 / 5816

页数：4

共 5 条

[1]

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[2] STEREOSELECTIVE SYNTHESIS OF CIS-2,3-DIARYLAZIRIDINE BY REARRANGEMENT OF ARYL-SUBSTITUTED N-(SILYLMETHYL)IMINE [J].

KOMATSU, M ;

OHNO, M ;

TSUNO, S ;

OHSHIRO, Y .

CHEMISTRY LETTERS, 1990, (04) :575-576

[3]

LOWN JW, 1984, 1 3 DIPOLAR CYCLOADD, V2, P653

[4]

OHNO M, IN PRESS

[5] OBSERVATIONS ON SCOPE OF PHOTOINDUCED 1,3-DIPOLAR ADDITION-REACTIONS OF ARYLAZIRINES [J].

PADWA, A ;

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SMOLANOF.J ;

WETMORE, SI .

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