STUDIES ON SODIUM SULFOPROPYLALKYL MALEATE SURFACTANTS - AGGREGATION BEHAVIOR

被引：16

作者：

GOEBEL, KH ^{[1
]}

STAHLER, K ^{[1
]}

VONBERLEPSCH, H ^{[1
]}

机构：

[1] MAX PLANCK INST KOLLOID & GRENZFLACHENFORSCH,KANTSTR 55,D-14513 TELTOW,GERMANY

来源：

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 1994年 / 87卷 / 02期

关键词：

CRITICAL MICELLE CONCENTRATION; ELECTRICAL CONDUCTIVITY; KRAFFT DISCONTINUITY; SURFACE TENSION;

D O I：

10.1016/0927-7757(94)02775-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The synthesis of a homologous series of sodium sulfopropylalkyl maleates with chain lengths of 12, 14 and 18 hydrocarbon groups, respectively, is briefly described. The CMCs in aqueous solution have been estimated from electrical conductivity and surface tension studies. The C18 homologue is distinguished by its unexpectedly low CMC value and the appearance of a distinct Krafft discontinuity at 37-degrees-C as determined by conductivity measurements and differential scanning calorimetry. It is suggested that the presence of the cis double bond in the molecule leads to the unusual aggregation behaviour of the surfactants.

引用

页码：143 / 149

页数：7

共 21 条

[1]

Cevc G., 1987, PHOSPHOLIPID BILAYER

[2] THE EFFECT OF SALTS AND CHAIN LENGTH ON THE CRITICAL CONCENTRATIONS OF COLLOIDAL ELECTROLYTES [J].

CORRIN, ML .

JOURNAL OF COLLOID SCIENCE, 1948, 3 (04) :333-338

[3] ALKYL SULPHATES .1. CRITICAL MICELLE CONCENTRATIONS OF THE SODIUM SALTS [J].

EVANS, HC .

JOURNAL OF THE CHEMICAL SOCIETY, 1956, (MAR) :579-586

[4]

GARCIAMATEOS I, 1990, LANGMUIR, V6, P111

[5] MICELLIZATION STUDY OF SODIUM DODECYL-SULFATE IN WATER AND MICROEMULSION SYSTEMS BY CONDUCTIVITY AND COUNTERION-ACTIVITY MEASUREMENTS [J].

GEORGES, J ;

CHEN, JW .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1986, 113 (01) :143-153

[6] SURFACTANT STRUCTURE AND ITS RELATION TO THE KRAFFT POINT, CLOUD POINT AND MICELLIZATION - SOME EMPIRICAL RELATIONSHIPS [J].

GU, TR ;

SJOBLOM, J .

COLLOIDS AND SURFACES, 1992, 64 (01) :39-46

[7] KINETIC AND THERMODYNAMIC MEASUREMENTS ON AGGREGATION OF PERFLUORINATED SURFACTANTS [J].

HOFFMANN, H ;

ULBRICHT, W .

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT, 1977, 106 (3-6) :167-184

[8] CHARACTERIZATION OF MICELLAR SOLUTIONS USING SURFACTANT ION ELECTRODES [J].

KALE, KM ;

CUSSLER, EL ;

EVANS, DF .

JOURNAL OF PHYSICAL CHEMISTRY, 1980, 84 (06) :593-598

[9]

KOZUKA, 1976, Patent No. 3980622

[10] DYNAMIC PROPERTIES OF ADSORPTION LAYERS OF AMPHIPHILIC SUBSTANCES AT FLUID INTERFACES [J].

KRETZSCHMAR, G ;

MILLER, R .

ADVANCES IN COLLOID AND INTERFACE SCIENCE, 1991, 36 :65-124

← 1 2 3 →