MCPBA OXIDATION OF BICYCLO[3.3.0]OCTANE-3,7-DIONE - AN EASY ENTRY TO A NEW FUNCTIONALIZED CYCLOPENTANOID BUILDING BLOCK

被引：11

作者：

GARLASCHELLI, L ^{[1
]}

VIDARI, G ^{[1
]}

ZANONI, G ^{[1
]}

机构：

[1] UNIV PAVIA,DIPARTIMENTO CHIM ORGAN,V TARAMELLI 10,I-27100 PAVIA,ITALY

来源：

TETRAHEDRON | 1992年 / 48卷 / 43期

关键词：

D O I：

10.1016/S0040-4020(01)88317-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alteration of the C2V symmetry of cis-bicyclo[3.3.0]octane-3,7-dione was achieved by a MCPBA controlled Baeyer-Villiger oxidation. Cis-3-oxabicyclo[4.3.0] nonane-4,8-dione (3) thus obtained was used in a formal synthesis of (+/-)-loganin (4).

引用

页码：9495 / 9502

页数：8

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